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- W2012000668 abstract "Treatment of α-nitro ketone tosylhydrazones with DBU gives 1,4-elimination of nitrous acid affording 1-tosylazoalkenes which, under basic conditions (DBU), tautomerize to the more stable enone tosylhydrazones. The obtained tosylhydrazones may be used as starting material for a wide range of other functionalities. Removal of the hydrazone affords conjugated enones in good yields. Due to the possibility to prepare the nitro ketones with the nitro group in α or α′ position, by this method it is possible to obtain α,β-unsaturated carbonyl compounds with the complete regioselectivity." @default.
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- W2012000668 date "1995-04-01" @default.
- W2012000668 modified "2023-10-15" @default.
- W2012000668 title "A novel reactivity of α-nitro ketone tosylhydrazones with DBU. Synthesis of α,β-unsaturated enone tosylhydrazones" @default.
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- W2012000668 doi "https://doi.org/10.1016/0040-4020(95)00133-s" @default.
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