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- W2012007199 abstract "The extended X-ray absorption fine structure (EXAFS) study of K 1- x (NH 4 ) x I and KBr 1- x (NO 2 ) x mixed crystals was performed to elucidate the local structure of their glassy state associated with the reorientational freezing of molecular ions without any long-range order. The magnitude of EXAFS spectra of K 1- x (NH 4 ) x I was reduced with increasing ammonium ion concentration, while that of KBr 1- x (NO 2 ) x exhibits no anomalous changes with increasing nitrite ion concentration even below the glass transition temperature T g . The results indicate that the local distortion which breaks the symmetry of fcc lattice is induced by the short-range antiferroelectric order of ammonium ions in K 1- x (NH 4 ) x I and the local structure is retained by the short-range ferroelectric order of nitrite ions in KBr 1- x (NO 2 ) x . The temperature dependence of mean-square displacement of bromine-potassium pair-distribution in KBr 1- x (NO 2 ) x obeys the Debye approximation even below T g , which conflicts the result of previous X-ray diffraction studies that the mean-square displacement deviates largely from the Debye approximation." @default.
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- W2012007199 date "1999-01-01" @default.
- W2012007199 modified "2023-09-25" @default.
- W2012007199 title "EXAFS Study of Orientational Glasses" @default.
- W2012007199 doi "https://doi.org/10.7567/jjaps.38s1.152" @default.
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