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- W2012017062 abstract "We report herein a practical synthesis of 4'-thiothymidine (15) and appropriately protected 2'-deoxy-4'-thiocytidine (16), -thioadenosine (27), and -thioguanosine (29) derivatives, substrates for the synthesis of 4'-thioDNA, from the corresponding 4'-thioribonucleosides. 2'-deoxy-4'-thiopyrimidine nucleosides were synthesized using a radical reaction of the corresponding 2'-alpha-bromo derivatives, which were prepared via 2,2'-O-anhydro derivatives. 2'-deoxy-4'-thiopurine nucleosides were synthesized using the same radical reaction of the corresponding 2'-beta-bromo derivatives." @default.
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- W2012017062 date "2005-09-21" @default.
- W2012017062 modified "2023-10-17" @default.
- W2012017062 title "Practical Synthesis of 2‘-Deoxy-4‘-thioribonucleosides: Substrates for the Synthesis of 4‘-ThioDNA" @default.
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- W2012017062 doi "https://doi.org/10.1021/jo051248f" @default.
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