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- W2012020596 abstract "The structure of the title complex is built up of positively charged zigzag chains running parallel to the b axis with the composition cis[-μ-CN-Cu(bpy) 2 -μ-NC-Ag-] + (bpy=2,2'-bipyridine), isolated [Ag(CN) 2 ] - anion and non-coordinated water molecule. The Cu atom is coordinated in the form of a very deformed tetragonal bipyramid (4+1+1) with unequal distortion of the axial bonds [2.239 (4) and 2.676 (5) A]. Three crystallographically independent Ag atoms are coordinated linearly by two cyano groups and they are placed along the b axis forming an infinite chain with short Ag...Ag distances [3.0439 (4) and 2.9866 (4) A]" @default.
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- W2012020596 date "1993-07-15" @default.
- W2012020596 modified "2023-10-17" @default.
- W2012020596 title "catena-Poly[silver(I)-μ-(cyano-C:N)-cis-bis(2,2'-bipyridine-N,N')copper(II)-μ-(cyano-N:C)] dicyanoargentate(I) monohydrate" @default.
- W2012020596 doi "https://doi.org/10.1107/s010827019300037x" @default.
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