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- W2012024286 abstract "Abstract The thermal decomposition of azomethane (A) has been studied in a static system at temperatures between 250° and 320°C and at pressures between 5 and 402 torr, with particular attention to identification of products. Major products, in decreasing order of importance, were nitrogen, methane, ethane, methylethyldiimide, dimethylhydrazone, propane, tetramethylhydrazine, ethylene, methylpropyldiimide, and methylethylhydrazone. Carbon balance at the lowest pressure and highest temperature was 92%, but decreased with increasing pressure and decreasing temperature owing to the formation of a polymer. A fairly simple mechanism accounts reasonably well for a short chain in the decomposition, propagated by the radical CH 3 N 2 CH 2 (B), and for the five most abundant products, except ethane. It turns out that there is a second source of ethane, arising by C 2 H 5 + A → C 2 H 6 + B; this explains an anomalously high apparent activation energy for the reaction CH 3 + A → CH 4 + B. Ethyl radicals are also shown to be responsible for the formation of propane, ethylene, methylethylhydrazone, and methylpropyldiimide. The radical B decomposes to CH 3 + CH 2 + N 2 , and the methylene radical (probably both singlet and triplet) is shown to yield C 2 H 5 at low pressure and high temperature, and mostly polymer at high pressure and low temperature." @default.
- W2012024286 created "2016-06-24" @default.
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- W2012024286 date "1973-07-01" @default.
- W2012024286 modified "2023-10-10" @default.
- W2012024286 title "The thermal decomposition of azomethane. III. Kinetics of the noninhibited reaction" @default.
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- W2012024286 doi "https://doi.org/10.1002/kin.550050418" @default.
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