FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012032191> ?p ?o ?g. }

• W2012032191 endingPage "732" @default.
• W2012032191 startingPage "724" @default.
• W2012032191 abstract "Red needle-like crystals of the title compound were grown using a reaction between Bi metal and methyl iodide under solvothermal conditions. CH3BiI2 crystallizes in the monoclinic space group C2/m with an unusual one-dimensional organic−inorganic chain-like structure. The Bi atoms have a square pyramidal local geometry, with four I atoms forming the base and one methyl group occupying an apical site. Each basal square shares trans edges with two nearest neighbors to form a one-dimensional inorganic BiI2 chain along the b-axis. All methyl groups are covalently bonded to bismuth atoms and are aligned on one side of the BiI2 basal plane. The organic−inorganic chains are held together via van der Waals interaction, forming an extended solid state structural array. Extended Hückel band structure calculations demonstrate electronic one-dimensionality for CH3BiI2. Molecular modeling suggests that the square pyramidal Bi coordination arises primarily to reduce Bi−C antibonding character in the HOMO. The resulting Bi 6s and 6p hybridization in the valence band (HOMO) leads to a stereochemically active lone pair oriented trans to each methyl group. Thermal stability and decomposition of the title compound is examined using GC mass spectroscopy and simultaneous TGA and DTA techniques. CH3BiI2 begins to decompose at 185 °C in an inert atmosphere into methyl iodide and bismuth monoiodide, providing a new pathway to the formation of the interesting low valency one-dimensional conductor, BiI." @default.
• W2012032191 created "2016-06-24" @default.
• W2012032191 creator A5001331359 @default.
• W2012032191 creator A5015968273 @default.
• W2012032191 creator A5021246220 @default.
• W2012032191 creator A5024058183 @default.
• W2012032191 creator A5056808182 @default.
• W2012032191 date "1997-01-01" @default.
• W2012032191 modified "2023-09-26" @default.
• W2012032191 title "Synthesis and Solid State Chemistry of CH₃BiI₂: A Structure with an Extended One-Dimensional Organometallic Framework" @default.
• W2012032191 cites W1965802269 @default.
• W2012032191 cites W1966418759 @default.
• W2012032191 cites W1969815211 @default.
• W2012032191 cites W1971733465 @default.
• W2012032191 cites W1972489473 @default.
• W2012032191 cites W1981458170 @default.
• W2012032191 cites W1982983233 @default.
• W2012032191 cites W1987863138 @default.
• W2012032191 cites W1988304487 @default.
• W2012032191 cites W1992477591 @default.
• W2012032191 cites W1998815615 @default.
• W2012032191 cites W2000794409 @default.
• W2012032191 cites W2013992667 @default.
• W2012032191 cites W2018094461 @default.
• W2012032191 cites W2020501790 @default.
• W2012032191 cites W2022805549 @default.
• W2012032191 cites W2022960413 @default.
• W2012032191 cites W2023552583 @default.
• W2012032191 cites W2025243023 @default.
• W2012032191 cites W2025983387 @default.
• W2012032191 cites W2031454402 @default.
• W2012032191 cites W2035982983 @default.
• W2012032191 cites W2036363681 @default.
• W2012032191 cites W2037365597 @default.
• W2012032191 cites W2040829908 @default.
• W2012032191 cites W204759794 @default.
• W2012032191 cites W2049074020 @default.
• W2012032191 cites W2050570809 @default.
• W2012032191 cites W2051088825 @default.
• W2012032191 cites W2052129390 @default.
• W2012032191 cites W2053703206 @default.
• W2012032191 cites W2053909549 @default.
• W2012032191 cites W2064491332 @default.
• W2012032191 cites W2066630749 @default.
• W2012032191 cites W2067392374 @default.
• W2012032191 cites W2074326946 @default.
• W2012032191 cites W2083564567 @default.
• W2012032191 cites W2092232937 @default.
• W2012032191 cites W2112588985 @default.
• W2012032191 cites W2148095955 @default.
• W2012032191 cites W2344889448 @default.
• W2012032191 cites W4243186373 @default.
• W2012032191 cites W4245791942 @default.
• W2012032191 cites W4247469428 @default.
• W2012032191 doi "https://doi.org/10.1021/ja961753h" @default.
• W2012032191 hasPublicationYear "1997" @default.
• W2012032191 type Work @default.
• W2012032191 sameAs 2012032191 @default.
• W2012032191 citedByCount "43" @default.
• W2012032191 countsByYear W20120321912012 @default.
• W2012032191 countsByYear W20120321912013 @default.
• W2012032191 countsByYear W20120321912014 @default.
• W2012032191 countsByYear W20120321912015 @default.
• W2012032191 countsByYear W20120321912017 @default.
• W2012032191 countsByYear W20120321912018 @default.
• W2012032191 countsByYear W20120321912019 @default.
• W2012032191 countsByYear W20120321912021 @default.
• W2012032191 crossrefType "journal-article" @default.
• W2012032191 hasAuthorship W2012032191A5001331359 @default.
• W2012032191 hasAuthorship W2012032191A5015968273 @default.
• W2012032191 hasAuthorship W2012032191A5021246220 @default.
• W2012032191 hasAuthorship W2012032191A5024058183 @default.
• W2012032191 hasAuthorship W2012032191A5056808182 @default.
• W2012032191 hasConcept C115624301 @default.
• W2012032191 hasConcept C121332964 @default.
• W2012032191 hasConcept C138885662 @default.
• W2012032191 hasConcept C139007053 @default.
• W2012032191 hasConcept C147120987 @default.
• W2012032191 hasConcept C168900304 @default.
• W2012032191 hasConcept C178790620 @default.
• W2012032191 hasConcept C179104552 @default.
• W2012032191 hasConcept C185592680 @default.
• W2012032191 hasConcept C189394030 @default.
• W2012032191 hasConcept C2778870691 @default.
• W2012032191 hasConcept C32909587 @default.
• W2012032191 hasConcept C41895202 @default.
• W2012032191 hasConcept C46000676 @default.
• W2012032191 hasConcept C533668322 @default.
• W2012032191 hasConcept C61276311 @default.
• W2012032191 hasConcept C62520636 @default.
• W2012032191 hasConcept C71240020 @default.
• W2012032191 hasConcept C8010536 @default.
• W2012032191 hasConcept C92840921 @default.
• W2012032191 hasConcept C95269574 @default.
• W2012032191 hasConceptScore W2012032191C115624301 @default.
• W2012032191 hasConceptScore W2012032191C121332964 @default.
• W2012032191 hasConceptScore W2012032191C138885662 @default.
• W2012032191 hasConceptScore W2012032191C139007053 @default.

• next