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- W2012037669 abstract "The reactivity of vanadium complexes bearing the ligand dipicolinic acid (H2dipic) with alcohols has been explored. Dipic vanadium complexes are able to catalyze the aerobic oxidative C−C bond cleavage of pinacol. Reaction under anaerobic conditions allowed for isolation of a VIII μ-oxo dimer, supporting the involvement of VIII in aerobic oxidation reactions. Stoichiometric oxidation of unactivated aliphatic alcohols has also been observed, with oxidation of cyclobutanol producing cyclobutanone in 93% yield. The absence of ring-opening products in this reaction provides further support for the involvement of VIII intermediates." @default.
- W2012037669 created "2016-06-24" @default.
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- W2012037669 date "2008-12-22" @default.
- W2012037669 modified "2023-10-14" @default.
- W2012037669 title "Aerobic Oxidation of Pinacol by Vanadium(V) Dipicolinate Complexes: Evidence for Reduction to Vanadium(III)" @default.
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- W2012037669 doi "https://doi.org/10.1021/ja807522n" @default.
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