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- W2012042016 abstract "The reaction of toluene solutions of FeTPPCl with RSH (R = CH3 or (CH3)3C) in the presence of pyridine has been studied by epr and electronic spectra. The reaction results in the reduction of FeTPPCl to FeTPP(Py)2 and the oxidation of RSH to R2S2. Kinetic data obtained for the reaction shows the observed rate law to be: −d[ Fe TTPCl]/I d t = k[ Fe TPPCl][ R SH][ Py ] 3 Epr studies show the involvement of two paramagnetic, S = 1/2, intermediates. The first intermediate is assigned as FeTPP(Py)(SR), while the second intermediate is postulated as FeTPP(Py)2(RS). Possible structures for this second intermediate are discussed. A mechanism is proposed which it consistant with the observed data. The intocatalytic nature of this system is also described." @default.
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- W2012042016 title "Spectroscopic and kinetic studies of the reactions of iron(III) porphyrins with alkyl thiols" @default.
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- W2012042016 doi "https://doi.org/10.1016/s0020-1693(00)94765-0" @default.
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