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• W2012060010 abstract "Millimolar bulk concentrations of the surfactant cetyltrimethylammonium bromide (CTAB) induce spreading of alkanes, H(CH(2))(n)H (denoted C(n)) 12< or =n< or =21, on the water surface, which is not otherwise wet by these alkanes. The novel Langmuir-Gibbs film (LGF) formed is a liquidlike monolayer comprising both alkanes and CTAB tails. Upon cooling, an ordering transition occurs, yielding a hexagonally packed, quasi-2D crystal. For 11< or =n< or =17 this surface-frozen LGF is a crystalline monolayer. For 18< or =n< or =21 the LGF is a bilayer with a crystalline, pure-alkane, upper monolayer, and a liquidlike lower monolayer. The phase diagram and film structure were determined by x-ray, ellipsometry, and surface tension measurements. A thermodynamic theory accounts quantitatively for the observations." @default.
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• W2012060010 date "2007-09-28" @default.
• W2012060010 modified "2023-09-23" @default.
• W2012060010 title "Wetting, Mixing, and Phase Transitions in Langmuir-Gibbs Films" @default.
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• W2012060010 doi "https://doi.org/10.1103/physrevlett.99.136102" @default.
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