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- W2012068151 abstract "The successive addition of ROH (R=CH3 and C2H5) to the dichloromethane solution of MovO(tpp)Br (tpp=meso-tetraphenylporphinato) causes two-step reactions at 25 °C. The products of the first and the second step of the reactions are alcohol complex, [MovO(tpp)(ROH)]Br, and alkoxo complex, MovO(tpp)OR, respectively. In the presence of superoxide ion, O2−, in the dichloromethane solution of MovO(tpp)X (X=Br and NCS) containing alcohol, MovO(tpp)OR is formed through competitive two reaction paths where O2− acts as a proton acceptor and a reducing agent. The reaction steps of the two paths were confirmed by optical and ESR studies." @default.
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- W2012068151 date "1984-01-01" @default.
- W2012068151 modified "2023-10-18" @default.
- W2012068151 title "Mechanism of the Reactions of Oxomolybdenum(V) Tetraphenylporphyrin Complex with Alcohols in the Presence of Superoxide" @default.
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- W2012068151 doi "https://doi.org/10.1246/bcsj.57.194" @default.
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