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• W2012073640 abstract "The effect of the steric volume at C-19 of (3S)-2,3-oxidosqualene 1 on the polycyclization reaction by β-amyrin synthase was examined. The substrate analogs, in which the methyl group at C-19 of 1 was substituted by an ethyl group and hydrogen atom, were converted into the following three new compounds: (17β-H, 20S)-20-ethyl-dammara-12,24-diene 9, β-amyrin homologue 10, and the 6,6,6,6-fused tetracycle 11. The folding conformations leading to these products are discussed." @default.
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• W2012073640 date "2014-06-24" @default.
• W2012073640 modified "2023-10-08" @default.
• W2012073640 title "β-Amyrin Biosynthesis: The Critical Role of Steric Volume at C-19 of 2,3-Oxidosqualene for Its Correct Folding To Generate the Pentacyclic Scaffold" @default.
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• W2012073640 doi "https://doi.org/10.1021/ol501498q" @default.
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