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- W2012077876 abstract "To produce isoparaffins directly from synthesis gas, the mixture of CO and H2, modified Fischer−Tropsch (FT) synthesis was carried out using a hybrid catalyst consisting of Co/SiO2 and HZSM-5 under supercritical n-butane circumstances. Introduction of supercritical-phase n-butane increased light isoparaffins significantly and suppressed the formation of the byproduct, methane. Under supercritical-phase butane, hydrogenolysis and isomerization reactions were promoted. It is considered that because of high solubility of supercritical-phase n-butane, heavy hydrocarbons and water, the byproduct from FT synthesis, were removed quickly from acidic sites of zeolite; thus, hydrogenolysis and isomerization reactions of hydrocarbons were promoted." @default.
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- W2012077876 date "2008-07-02" @default.
- W2012077876 modified "2023-10-16" @default.
- W2012077876 title "One-Step Synthesis of Isoparaffin from Synthesis Gas Using Hybrid Catalyst with Supercritical Butane" @default.
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- W2012077876 doi "https://doi.org/10.1021/ef800205c" @default.
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