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• W2012080169 abstract "Reaction of Pd(OAc)2 with the Schiff base ligands 3,4-{O(CH2)nO}C6H3C(H)NR (n=1, 2; R=Cy, 3,4-(OCH2O)C6H3CH2-) leads to dinuclear cyclometallated products in which each palladium atom is C,N bonded to a deprotonated organic ligand, and to two acetate groups which bridge both metal centers. Treatment of 3,4-{O(CH2)2O}C6H3C(H)NCH2CH2NMe2 with [PtMe2(COD)] gives mononuclear compounds with the ligand as terdentate through the [C, N, N] atoms. The regioselectivity of the cyclometallation processes is discussed by 1H-NMR spectroscopy and X-ray diffraction studies." @default.
• W2012080169 created "2016-06-24" @default.
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• W2012080169 date "2000-03-01" @default.
• W2012080169 modified "2023-09-22" @default.
• W2012080169 title "Influence of phenyl ring substituents in the cyclometallation of Schiff base ligands: crystal and molecular structures of [Pd-{3,4-(OCH2O)C6H2C(H)N(Cy)-C2,N}(μ-O2CMe)]2 and [Pd-{3,4-(OCH2CH2O)C6H2C(H)N(Cy)-C6,N}(μ-O2CMe)]2" @default.
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• W2012080169 doi "https://doi.org/10.1016/s0022-328x(99)00680-4" @default.
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