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- W2012085170 abstract "Abstract The solubilities of chromium(III) acetylacetonate, uranyl acetylacetonate monohydrate, and the uranyl oxinate complex containing an additional molecule of oxine have been determined in several solvents over a range of temperatures. These solutions appear to conform approximately to Hildebrand's criteria for regular solutions. The solubility parameters of these complexes have been evaluated, and the thermodynamic functions for the solution processes have been calculated. The constancy of the solubility parameters toward various solvents suggests the possibility of prediction of the solubilities of these materials in non-polar solvents. The molal volumes of solutions of some highly symmetrical octahedral complexes in benzene are found to be represented very accurately by a linear equation in terms of mole fraction. The prediction of solubility parameters from the structural features of the inner complex salts is possible by the extension of Small's procedure for organic compounds." @default.
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- W2012085170 date "1961-12-01" @default.
- W2012085170 modified "2023-09-27" @default.
- W2012085170 title "Thermodynamics of solution of some inner complex salts" @default.
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