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• W2012087181 endingPage "4391" @default.
• W2012087181 startingPage "4383" @default.
• W2012087181 abstract "New filled skutterudites LnFe4P12 (Ln = Ho, Er, Tm and Yb) and YRu4P12 with heavy lanthanide (including Y) have been prepared at high temperatures and high pressures. Electrical and magnetic properties of these compounds have been studied at low temperatures. The magnetic susceptibility of HoFe4P12 and ErFe4P12 follows the Curie–Weiss behaviour at higher temperatures. The linear slope of χ−1 versus T curves yields effective magnetic moments of 10.43 μB for HoFe4P12 and 9.59 μB for ErFe4P12. These values are in good agreement with magnetic moments of Ho3+ and Er3+ ions calculated from Hund's rule, 10.60 and 9.69 μB, respectively. HoFe4P12 shows a ferromagnetic transition at around 5 K. TmFe4P12 and YbFe4P12 exhibit the paramagnetic behaviour at low temperatures. The lattice constant of YbFe4P12 is 7.7877(5) Å, larger than the value expected from the skutterudite compounds with the oxidation state of +3. This compound may be in an intermediate valence state. YRu4P12 shows the superconducting transition at around 8.5 K. This compound is a new superconductor. The Tc of YRu4P12 is higher than that of YFe4P12 and YOs4P12, and is highest among the metal phosphides with a skutterudite-type structure." @default.
• W2012087181 created "2016-06-24" @default.
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• W2012087181 date "2005-06-24" @default.
• W2012087181 modified "2023-10-01" @default.
• W2012087181 title "Electrical and magnetic properties of new filled skutterudites LnFe₄P₁₂(Ln = Ho, Er, Tm and Yb) and YRu₄P₁₂with heavy lanthanide (including Y) prepared at high pressure" @default.
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• W2012087181 doi "https://doi.org/10.1088/0953-8984/17/27/013" @default.
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