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- W2012087423 abstract "AsOCl3 entsteht durch Ozonolyse von AsCl3. Es ist pyramidal gebaut mit starker AsO Doppelbindung. Bei Raumtemperatur zersetzt es sich zu (As2O3Cl4)n, dessen Struktur noch unbekannt ist. Entsprechende Oxidbromide AsOBr3 und As2O3Br4 sind so nicht darstellbar, ebensowenig ein Oxidfluorid AsOF3. Arsentrichlorid reagiert mit elementarem Fluor unter vorsichtiger Reaktionsfuhrung zu AsCl4+AsF6−.Oxide Chlorides of Arsenic (V): AsOCl3 and (As2O3Cl4)nAsOCl3 is formed by ozonolysis of AsCl3. It has a pyramidal structure with a strong AsO double bond. At room temperature it decomposes to (As2O3Cl4)n of unknown structure. Similar oxide bromides AsOBr3 and As2O3Br4 and oxide fluorides AsOF3 are not formed.Arsenic trichloride reacts with elemental fluorine under carefully controlled conditions to AsCl4+AsF6−." @default.
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- W2012087423 date "1978-04-01" @default.
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- W2012087423 title "Oxidchloride des Arsen(V): AsOCl3 und (As2O3Cl4)n" @default.
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- W2012087423 doi "https://doi.org/10.1002/zaac.19784390101" @default.
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