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• W2012093823 abstract "Oxidation of a doubly cyclometallated platinum(II) complex results in two isomeric platinum(IV) complexes. Whereas the trans isomer is robust, being manipulable in air at room temperature, the cis isomer decomposes at −20 °C and above. Reductive coupling of an alkyl chloride at the cis isomer gives a new species which can be reoxidised. The independence of this coupling on additional halide rules out the reverse of an SN2 reaction, leaving a concerted process as the only sensible reaction pathway." @default.
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• W2012093823 date "2012-01-01" @default.
• W2012093823 modified "2023-10-17" @default.
• W2012093823 title "Concerted reductive coupling of an alkyl chloride at Pt(iv)" @default.
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• W2012093823 doi "https://doi.org/10.1039/c2cc31572f" @default.
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