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- W2012103373 abstract "Treatment of Li{CH(SiMe3)Ar}(tmeda)(Ar = 9-anthryl, tmeda = Me2N[CH2]2NMe2) with zirconocene(IV) chloride in tetrahydrofuran at 20 °C affords [Zr{CH(SiMe3)Ar}Cl(η-C5H5)2], which rapidly reacts with carbon monoxide (PCO 1 atm, 20 °C) in toluene to afford exclusively the E-metallo-enolate [Zr{OC(SiMe3)CHAr}Cl(η-C5H5)2], having Zr–O 1.950(4)Å and < Zr–O–C 157.7(3)°." @default.
- W2012103373 created "2016-06-24" @default.
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- W2012103373 date "1985-01-01" @default.
- W2012103373 modified "2023-10-16" @default.
- W2012103373 title "Stereospecific synthesis of a metallo-enolate: E-[Zr{OC(SiMe<sub>3</sub>)CHAr}Cl(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>](structurally characterised)via carbonylation of [Zr{CH(SiMe<sub>3</sub>)Ar}Cl(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>](Ar = 9-anthryl)" @default.
- W2012103373 doi "https://doi.org/10.1039/c39850000521" @default.
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