Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012104992> ?p ?o ?g. }
- W2012104992 endingPage "324" @default.
- W2012104992 startingPage "317" @default.
- W2012104992 abstract "The fundamental (Δv = 1 ← 0) and the first overtone (Δv = 2 ← 0) transitions of monolayer physisorbed CO on NaCl(100) single crystal surfaces at 5 K have been investigated using polarized Fourier transform infrared spectroscopy. Comparisons of the transition frequencies, bandwidths and absorbances for these two transitions together with those of dilute isotopes allow us to isolate the contribution of dynamic and static coupling effects of molecules within the monolayer. Homogeneous and heterogeneous effects can also be distinguished from band profiles of these various transitions. We conclude that the residual line broadening of 0.1 cm−1 at 5 K for the isolated CO isotopes arises from heterogeneous surface effects. We set an upper limit of 0.07 cm−1 for the linewidth of single CO molecules on NaCl(lOO) due to surface heterogeneity. A lower limit of × 10−8 cm−1 is provided by the vibrational lifetime of adsorbed CO molecules. Sharpness of the vibrational features shows that infrared spectroscopy of adsorbate is a sensitive method for probing surface and adlayer irregularities of adsorbed molecules on a single crystal." @default.
- W2012104992 created "2016-06-24" @default.
- W2012104992 creator A5024663053 @default.
- W2012104992 creator A5064879646 @default.
- W2012104992 creator A5065102952 @default.
- W2012104992 date "1995-04-01" @default.
- W2012104992 modified "2023-09-24" @default.
- W2012104992 title "Vibrational Spectroscopy As a Probe of Surface Heterogeneity: CO on NaCl(100)" @default.
- W2012104992 cites W106975610 @default.
- W2012104992 cites W186205853 @default.
- W2012104992 cites W1966349123 @default.
- W2012104992 cites W1967461304 @default.
- W2012104992 cites W1970278164 @default.
- W2012104992 cites W1979271878 @default.
- W2012104992 cites W1982887529 @default.
- W2012104992 cites W1984225214 @default.
- W2012104992 cites W1985474014 @default.
- W2012104992 cites W1991169801 @default.
- W2012104992 cites W1991982193 @default.
- W2012104992 cites W1992732358 @default.
- W2012104992 cites W1996539910 @default.
- W2012104992 cites W2009623179 @default.
- W2012104992 cites W2010979749 @default.
- W2012104992 cites W2016159059 @default.
- W2012104992 cites W2022039555 @default.
- W2012104992 cites W2024031140 @default.
- W2012104992 cites W2024568801 @default.
- W2012104992 cites W2030731325 @default.
- W2012104992 cites W2033014123 @default.
- W2012104992 cites W2033961392 @default.
- W2012104992 cites W2035371021 @default.
- W2012104992 cites W2035871208 @default.
- W2012104992 cites W2046957804 @default.
- W2012104992 cites W2047026055 @default.
- W2012104992 cites W2051887492 @default.
- W2012104992 cites W2053968362 @default.
- W2012104992 cites W2054519240 @default.
- W2012104992 cites W2062360754 @default.
- W2012104992 cites W2063140846 @default.
- W2012104992 cites W2066525741 @default.
- W2012104992 cites W2078469254 @default.
- W2012104992 cites W2088696868 @default.
- W2012104992 cites W2144040446 @default.
- W2012104992 cites W2921577402 @default.
- W2012104992 cites W4250103221 @default.
- W2012104992 doi "https://doi.org/10.1002/jccs.199500043" @default.
- W2012104992 hasPublicationYear "1995" @default.
- W2012104992 type Work @default.
- W2012104992 sameAs 2012104992 @default.
- W2012104992 citedByCount "11" @default.
- W2012104992 countsByYear W20121049922013 @default.
- W2012104992 countsByYear W20121049922017 @default.
- W2012104992 countsByYear W20121049922021 @default.
- W2012104992 crossrefType "journal-article" @default.
- W2012104992 hasAuthorship W2012104992A5024663053 @default.
- W2012104992 hasAuthorship W2012104992A5064879646 @default.
- W2012104992 hasAuthorship W2012104992A5065102952 @default.
- W2012104992 hasConcept C113196181 @default.
- W2012104992 hasConcept C120665830 @default.
- W2012104992 hasConcept C121332964 @default.
- W2012104992 hasConcept C1276947 @default.
- W2012104992 hasConcept C142181693 @default.
- W2012104992 hasConcept C153642686 @default.
- W2012104992 hasConcept C158355884 @default.
- W2012104992 hasConcept C164304813 @default.
- W2012104992 hasConcept C178790620 @default.
- W2012104992 hasConcept C185592680 @default.
- W2012104992 hasConcept C199360897 @default.
- W2012104992 hasConcept C24123453 @default.
- W2012104992 hasConcept C2781285689 @default.
- W2012104992 hasConcept C32891209 @default.
- W2012104992 hasConcept C32909587 @default.
- W2012104992 hasConcept C38615331 @default.
- W2012104992 hasConcept C41008148 @default.
- W2012104992 hasConcept C43617362 @default.
- W2012104992 hasConcept C4839761 @default.
- W2012104992 hasConcept C52003146 @default.
- W2012104992 hasConcept C520434653 @default.
- W2012104992 hasConcept C55493867 @default.
- W2012104992 hasConcept C62520636 @default.
- W2012104992 hasConcept C7070889 @default.
- W2012104992 hasConceptScore W2012104992C113196181 @default.
- W2012104992 hasConceptScore W2012104992C120665830 @default.
- W2012104992 hasConceptScore W2012104992C121332964 @default.
- W2012104992 hasConceptScore W2012104992C1276947 @default.
- W2012104992 hasConceptScore W2012104992C142181693 @default.
- W2012104992 hasConceptScore W2012104992C153642686 @default.
- W2012104992 hasConceptScore W2012104992C158355884 @default.
- W2012104992 hasConceptScore W2012104992C164304813 @default.
- W2012104992 hasConceptScore W2012104992C178790620 @default.
- W2012104992 hasConceptScore W2012104992C185592680 @default.
- W2012104992 hasConceptScore W2012104992C199360897 @default.
- W2012104992 hasConceptScore W2012104992C24123453 @default.
- W2012104992 hasConceptScore W2012104992C2781285689 @default.
- W2012104992 hasConceptScore W2012104992C32891209 @default.
- W2012104992 hasConceptScore W2012104992C32909587 @default.
- W2012104992 hasConceptScore W2012104992C38615331 @default.
- W2012104992 hasConceptScore W2012104992C41008148 @default.