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- W2012105467 abstract "Impedance spectra were measured for Pt(111) and Rh(111) electrodes in various electrolytes. They can all be interpreted by assuming one or two parallel adsorption resistances in addition to the double layer capacity. Adsorption of Cl− and HSO4− at Pt(111) is very fast and at the limit of detectability. Adsorption of H2PO4− has to be described by two parallel adsorption reactions, one of which is possibly an adsorption connected with deprotonation. Adsorption of hydrogen at Rh(111) is much slower than at Pt(111); surface roughness has opposing effects on both metals and leads to an increased adsorption rate at Rh." @default.
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- W2012105467 date "1998-11-01" @default.
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- W2012105467 title "The rate of anion and hydrogen adsorption on Pt(111) and Rh(111)" @default.
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- W2012105467 doi "https://doi.org/10.1016/s0013-4686(98)00194-7" @default.
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