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- W2012107506 abstract "The thiocyanate complexing of Np(IV), at μ = 2.0 and [H+] = 1.0 M, has been studied by solvent extraction method, using thenoyltrifluoroacetone (TTA) and dinonylnaphthalene-sulphanic acid (DNNS), and that of Pu(III), under similar conditions, using DNNS. Data indicate the formation of three successive complexes between Np(IV) and SCN− with the overall stability constants 31.3 ± 4.9, 114.7 ± 20.7 and 340.9 ± 18.3. Pu(III) seems to form only one complex upto [SCN−] ⩽ 0.4 M, with the stability constant value of 2.14 + 0.15, whereas further complexing appears to occur at higher concentrations of SCN−; the β2 is estimated to be about 0.5. Spectrophotometric and solvent extraction data obtained further confirmed the thiocyanate complexing of these two ions. The thermodynamic constants associated with the complex formation of Np(IV) with thiocyanate have also been determined." @default.
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- W2012107506 date "1978-01-01" @default.
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- W2012107506 title "Thiocyanate complexing of Np(IV) and Pu(III)" @default.
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- W2012107506 doi "https://doi.org/10.1016/0022-1902(78)80135-3" @default.
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