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- W2012109170 abstract "The total synthesis of (-)-mersicarpine was achieved in 10 steps from a known ketoester. Our synthesis features an Eschenmoser-Tanabe-type fragmentation to synthesize an alkyne unit containing a quaternary carbon center, a facile construction of the indole skeleton via a combination of a Sonogashira coupling and a gold(III) catalyzed cyclization, as well as a one-pot process to arrange the cyclic imine and the hemiaminal moieties. Our synthesis unambiguously confirmed the reported structure of (-)-mersicarpine including the absolute configuration." @default.
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- W2012109170 date "2010-02-03" @default.
- W2012109170 modified "2023-10-14" @default.
- W2012109170 title "Total Synthesis of (−)-Mersicarpine" @default.
- W2012109170 doi "https://doi.org/10.1021/ja9103233" @default.
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