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- W2012112306 abstract "Phosphor powder of Gd2Zr2O7 has been prepared by the urea combustion route. Phase evolution of the synthesized powder is determined by X-ray diffraction (XRD) technique. The structural environment between the Gd3+ and the zirconium oxide lattice has been investigated using electron paramagnetic resonance (EPR), diffuse reflectance and photoluminescence (PL) studies. The EPR spectrum of Gd2Zr2O7 phosphor exhibits a broad and intense signal at g≈2.0 and this has been attributed to Gd3+ ions in octahedral symmetry with strong dipolar interactions between Gd3+ ions. The intensity of the spectrum increases with temperature lowering from 296 to 110 K following the usual Boltzmann law. The g value is invariant with temperature variation. The diffuse reflectance spectrum exhibits two sharp and weak bands characteristic of Gd3+ ions in octahedral symmetry. The photoluminescence spectrum exhibits several bands characteristic of Gd3+ ions in octahedral symmetry." @default.
- W2012112306 created "2016-06-24" @default.
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- W2012112306 date "2013-05-01" @default.
- W2012112306 modified "2023-10-01" @default.
- W2012112306 title "Optical and EPR studies of Gd2Zr2O7 phosphors prepared via solution combustion method" @default.
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- W2012112306 doi "https://doi.org/10.1016/j.physb.2013.02.012" @default.
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