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- W2012119093 abstract "Abstract ESR spectra from two different Cu 2+ with [100] tetragonal symmetry were observed in NH 4 Cl single crystals. The spin‐Hamiltonian parameters for both centres were determined in the temperature range 4.2 to 453 °K where NH 4 Cl has the CsCl structure. The g ‐values and hyperfine constants for both centres show a marked anomaly in the vicinity of the λ‐point and significant variations over the whole temperature range. Both centres have essentially a |3 z 2 – r 2 〉 ground state, but with evidence of vibrational admixtures of the | x 2 – y 2 〉 state. In view of possible future calculations of the Cu 2+ spin polarization and radial wave function for the ground state, the lattice parameter of NH 4 Cl and NH 4 Cl:Cu was measured in the temperature range 105 to 453 °K." @default.
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- W2012119093 date "1967-01-01" @default.
- W2012119093 modified "2023-10-09" @default.
- W2012119093 title "ESR Studies of Cu2+ in NH4Cl Single Crystals between 4.2 and 453 °K. I. Spin-Hamiltonian Parameters and Lattice Constant for NH4Cl" @default.
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- W2012119093 doi "https://doi.org/10.1002/pssb.19670200119" @default.
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