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- W2012121345 abstract "Binary mixtures of SF6 + octane, + nonane, + hendecane, and + decahydronaphthalene,cis were investigated up to 140 MPa. Measurements were performed according to the synthetic method using an optical high pressure cell. - Going from SF6 + octane to SF6 + nonane the critical p(T)-curves show a continuous transition between the type of liquid-liquid (ll) phase equilibrium with upper critical solution temperatures (UCST) and the gas-gas (gg) equilibrium of the 2nd kind. For the SF6 + n-alkane systems there is a systematical shift of the high-pressure branches of the critical curves of about 20 K to higher temperatures per CH2-unit. The experimental results are discussed in comparison to computer calculations with two semiempirical equations of state. Solvent properties of SF6 are compared to those of CO2, CF4, and CHF3." @default.
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- W2012121345 date "1985-05-01" @default.
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- W2012121345 title "Fluid Phase Equilibria of Binary Mixtures of SF6 with Octane, Nonane, Hendecane, and Decahydronaphthalene,cis at Temperatures between 280 K and 440 K and at Pressures up to 140 MPa in Comparison to Mixtures of Hydrocarbons with CO2, CF4, and CHF3" @default.
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- W2012121345 doi "https://doi.org/10.1002/bbpc.19850890517" @default.
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