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• W2012121505 abstract "The adsorption geometry of perfluorinated copper-phthalocyanine molecules $({mathrm{F}}_{16}mathrm{CuPc})$ on Cu(111) and Ag(111) is studied using x-ray standing waves. A detailed, element-specific analysis taking into account nondipolar corrections to the photoelectron yield shows that on both surfaces the molecules adsorb in a lying down, but significantly distorted configuration. While on copper (silver) the central carbon rings reside 2.61 AA{} (3.25 AA{}) above the substrate, the outer fluorine atoms are located 0.27 AA{} (0.20 AA{}) further away from the surface. This nonplanar adsorption structure is discussed in terms of the outer carbon atoms in ${mathrm{F}}_{16}mathrm{CuPc}$ undergoing a partial rehybridization $(s{p}^{2}ensuremath{rightarrow}s{p}^{3}).$" @default.
• W2012121505 created "2016-06-24" @default.
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• W2012121505 date "2005-05-31" @default.
• W2012121505 modified "2023-10-12" @default.
• W2012121505 title "Adsorption-induced distortion of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mi mathvariant=normal>F</mml:mi><mml:mn>16</mml:mn></mml:msub><mml:mi>CuPc</mml:mi></mml:mrow></mml:math>on Cu(111) and Ag(111): An x-ray standing wave study" @default.
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• W2012121505 doi "https://doi.org/10.1103/physrevb.71.205425" @default.
• W2012121505 hasPublicationYear "2005" @default.
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