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- W2012124024 abstract "Electron transfer between N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) and a compacted TTF-TCNQ electrode was observed in 0.1M aqueous potassium chloride using cyclic voltammetry. The positions of cathodic and anodic peaks are at 0.20 – 0.22 V and 0.31 – 0.33 V, respectively, vs. a silver/silver chloride electrode, suggesting quasi-reversible electron transfer. This is the first demonstration of electron transfer between an organic solute and a molecular organic electrode. Mechanistic aspects of the electron transfer are discussed. Attempts to use the new conductor prepared from TTF and 2,3-dicyano-p-benzoquinone as an electrode were thwarted by partial solubility of the electrode in aqueous and alcoholic solutions." @default.
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- W2012124024 date "1982-03-01" @default.
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- W2012124024 title "Electron transfer between an organic solute and intrinsic molecular organic electrode" @default.
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- W2012124024 doi "https://doi.org/10.1016/0379-6779(82)90016-9" @default.
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