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- W2012132598 abstract "Using DMF, acetonitrile and alcohols as cosolvents, both polyfluoroalkyl iodides, such as Cl(CF2)nI (n=4, 6, 8; 1a–c) and F(CF2)nI (n=6, 8; 1d, e), and polyfluoroalkyl bromides, such as Cl(CF2)6Br (3b) and F(CF2)8Br (3e), react with sodium disulfite in neutral aqueous solution to give the corresponding sulfinates Cl(CF2)nSO2Na (n=4, 6, 8; 2a–c) and F(CF2)nSO2Na (n=6, 8; 2d, e) in good yield. In a similar manner, CF3CCl3 (4a) reacted with sodium disulfite to give CF3CCl2SO2Na (5a)." @default.
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- W2012132598 date "1994-06-01" @default.
- W2012132598 modified "2023-09-24" @default.
- W2012132598 title "Studies on sulfinatodehalogenation. XXIX. The sulfinatodehalogenation of primary polyfluoroalkyl iodides and bromides by sodium disulfite" @default.
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