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- W2012133047 abstract "The dicationic arene complexes [(p-cymene)Ru(PhCH2CH2[CH2]nOH)][OTf]2 and [Cp*Ir(PhCH2CH2[CH2]nOH)][OTf]2 (n = 1−2) react with K2CO3 to cleanly generate spirocyclic cyclohexadienyl complexes through intramolecular nucleophilic addition of the alkoxide at the ipso carbon of the arene ligand. When the internal nucleophile is the bulkier benzenesulfonamide group, cyclohexadienyl complexes derived from both ipso and ortho intramolecular nucleophilic addition are formed." @default.
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- W2012133047 date "2003-03-20" @default.
- W2012133047 modified "2023-09-27" @default.
- W2012133047 title "Spirocyclic and Bicyclic Cyclohexadienyl Complexes from Intramolecular Nucleophilic Addition Reactions in Dicationic Arene Complexes" @default.
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- W2012133047 doi "https://doi.org/10.1021/om030020k" @default.
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