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• W2012134625 abstract "The addition reactions of polar unsaturated compounds with various organogermanium compounds i.e., (Me3Ge)2X (X = NMe, O and S), have been studied. The relative order of reactivities was found to be NMe > O 》 > S. When phenyl isothiocyanate was used as an acceptor with (Me3Ge)2NMe and (Me3Ge)2O, β-elimination of (Me3Ge)2S was observed with the formation of phenylmethylcarbodiimide and phenyl isocyanate, respectively. This behaviour suggests that the reactivity of the trimethylgermyl group is similar to that of the corresponding trimethyltin group although the reactivity in both cases is generally low. For this reason the affinity of the trimethylgermyl group to the above heteroatoms must follow the sequence > O ≈ N." @default.
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• W2012134625 date "1972-01-01" @default.
• W2012134625 modified "2023-10-17" @default.
• W2012134625 title "Reactions of group IV organometallic compounds XXIV. Addition and subsequent elimination reactions of bis(trimethylgermyl) methylamide oxide and sulphide" @default.
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• W2012134625 doi "https://doi.org/10.1016/s0022-328x(00)88672-6" @default.
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