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- W2012140445 abstract "Abstract We report the synthesis and characterisation of unprecedented unstrained [2]diborametallocenophanes of zirconium and hafnium that bear the bulky octamethylfluorenyl (η 5 ‐C 29 H 36 ) system, the proligands of which were pre‐constructed by a two‐step synthesis. The compounds were fully characterised by NMR spectroscopy, MALDI‐TOF mass spectrometry and X‐ray diffraction analysis. Typical reactivities relevant to olefin polymerisation such as methylation and chloride abstraction were also investigated. Finally, a sterically demanding bis(octamethylfluorenyl) metallocene was prepared." @default.
- W2012140445 created "2016-06-24" @default.
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- W2012140445 date "2011-09-09" @default.
- W2012140445 modified "2023-10-18" @default.
- W2012140445 title "Sterically Demanding Hetero-Substituted [2]Borametallocenophanes of Group IV Metals: Synthesis, Structure and Reactivity" @default.
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- W2012140445 doi "https://doi.org/10.1002/chem.201101774" @default.
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