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- W2012140819 abstract "Abstract —A direct synthetic route, based on silver(I) assisted metal exchange reaction, to cationic bis-ligand complexes of copper(I) involving N-aryl-pyridine-2-aldimines (L, 1) has been studied. These complexes are obtained as their perchlorates, [Cu(L) 2 ]ClO 4 (2). They have been characterized with the help of spectroscopy and X-ray crystallography. The X-ray structure of [Cu(L 2 ) 2 ]ClO 4 , where L 2 is N-p-tolyl-pyridine-2-aldimine is reported. There are two crystallographically independent molecules in the asymmetric unit. The ligand L 2 coordinates in a bidentate manner providing a highly distorted tetrahedral geometry about copper. The complexes show highly resolved symmetrical 1 H NMR spectra. Intense MLCT absorptions are observed in the visible range. In methanol the CuL 2 2+ /CuL 2 + couple has E 1/2 ca, 0.35 V vs SCE at 298 K. The moderately high positive potential is brought about by the distortion in the geometry of CuL 2 2+ ." @default.
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- W2012140819 date "1996-07-01" @default.
- W2012140819 modified "2023-09-26" @default.
- W2012140819 title "Monovalent copper complexes of N-aryl-pyridine-2-aldimine. synthesis, characterization and structure" @default.
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- W2012140819 doi "https://doi.org/10.1016/0277-5387(96)00065-4" @default.
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