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- W2012141749 abstract "Abstract A new metal-organic framework, {[Co1.5(μ2-OH)(L)(bipy)0.5] ·0.5DMF}n (1) (H2L = (4,4′-(hexafluoroisopropylidene)bis(benzoic acid) and bipy = 4,4′-bipyridine), has been prepared under solvothermal conditions using flexible dicarboxylate and rigid N-donor co-ligands in the presence of Co(II) ion as the building blocks. The x-ray single-crystal diffraction analysis indicates that 1 possesses a three-dimensional (3D) layer–pillar structure with one-dimensional (1D) metal-carboxylate chain. The Co(II) ions are bridged by L2− to generate a two-dimensional (2D) sheet, which is further pillared by bipy into a 3D framework with {44.62}{45.65}2 topology. In addition, the variable-temperature magnetic susceptibility measurement indicates there exists an anti-ferromagnetic behavior between in the Co(II) ions of 1. Keywords: crystal structuremagnetismmetal-organic frameworkpillar" @default.
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- W2012141749 date "2011-08-01" @default.
- W2012141749 modified "2023-09-27" @default.
- W2012141749 title "A New 3D Metal-Organic Framework Based on a Flexible and Rigid Co-Ligand: Synthesis, Structure, and Magnetic Properties" @default.
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- W2012141749 doi "https://doi.org/10.1080/15533174.2011.591309" @default.
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