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• W2012142453 abstract "Abstract Racemic (1 R* ,2 R* )‐1,2‐dihydroxy‐[1‐ 13 C 1 ]propylphosphonic acid and 1‐hydroxy‐[1‐ 13 C 1 ]acetone were synthesized and fed to R. huakuii PMY1. Alanine and a mixture of valine and methionine were isolated as their N ‐acetyl derivatives from the cell hydrolysate by reversed‐phase HPLC and analyzed by NMR spectroscopy. It was found that the carbon atoms of the respective carboxyl groups were highly 13 C‐labeled (up to 65 %). Hydroxyacetone is therefore considered an obligatory intermediate of the biodegradation of fosfomycin by R. huakuii PMY1." @default.
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• W2012142453 date "2011-10-20" @default.
• W2012142453 modified "2023-09-25" @default.
• W2012142453 title "Studies on the Biodegradation of Fosfomycin: Synthesis of ¹³C‐Labeled Intermediates, Feeding Experiments with <i>Rhizobium huakuii</i> PMY1, and Isolation of Labeled Amino Acids from Cell Mass by HPLC" @default.
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• W2012142453 doi "https://doi.org/10.1002/chem.201100725" @default.
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