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- W2012142475 abstract "Leonard–Henderson–Barker perturbation theory is applied to a binary mixture of hard-core molecules with square wells. Molecules are of equal core sizes, equal ranges of forces, and equal well depths, but of a relatively weak unlike-pair depth. The effect of change in the weakness parameter a of an unlike pair is examined in detail on the topological nature of the chemical potential surface of the fluid phase and hence on the phase diagram. How a positive or heterogeneous azeotrope appears and how the critical line changes with a are clearly demonstrated. Three liquid phases can coexist in equilibrium in the same range of a." @default.
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- W2012142475 modified "2023-10-16" @default.
- W2012142475 title "Perturbation theoretical study of the fluid phase of a binary mixture of hard-core molecules with square wells. Chemical potential surface and phase diagram" @default.
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- W2012142475 doi "https://doi.org/10.1063/1.441461" @default.
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