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- W2012144145 abstract "One of the first studies concermng the mteractlon of acetylene with noble metal electrodes was made m the slxtles by Bockrls et al on polycrystallme Pt [l] They found a coulomblc efficiency for CO, production from acetylene oxldatlon of 100% In analysmg stationary current-potential curves the rate-determining step was proposed between the adsorbed acetylene molecules and adsorbed water However, a correspondmg study on gold has shown that acetylene was only partially oxldlzed to CO, with a coulomblc efficiency of about 60% [2] Chemical analySIS and IR spectra of the reaction products have mdlcated the absence of CHO and C=O species The most probable by-product seemed to be a polymer structure havmg conjugated (s=C bonds and -OH groups [2] Different results were reported by Cwlkhnskl et al [3,4] who have found partial oxldatlon products such as CH,COOH, CHOCHO, CH,OHCHO and HCHO formed after the anodlc oxldatlon of aqueous solutions of acetylene They proposed a stable Au-C,H, complex as an intermediate mvolvmg a preferential corrosion of the gold anode The structure of adsorbed acetylene on gold electrodes was studied by Weaver et al [5-71 using surface enhanced Raman spectroscopy (SERS) Multiple bands were observed m the triple bond region These frequencies were assigned to u-r alkyne-metal complexes m which the acetylene molecule lies flat on the surface Recently, it has been shown that the reactivity and adsorbate formation on gold electrodes depends" @default.
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- W2012144145 date "1994-05-01" @default.
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- W2012144145 title "On the adsorption of acetylene on gold in acid media studied by DEMS" @default.
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- W2012144145 doi "https://doi.org/10.1016/0022-0728(94)87110-8" @default.
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