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• W2012144519 startingPage "2878" @default.
• W2012144519 abstract "The strength of the H-bond donation by alcohols is reflected in the carbon−hydrogen bond of the H−C−O−H functional group. The one-bond 13C−1H spin−spin coupling constant of hexafluoroisopropanol (HFIP) correlates with the strength of the H-bond in various HFIP−amine complexes with a slope of ∼ −0.2 Hz in 1JCH per ∼1 kJ mol-1 increase in the H-bond enthalpy. The decrease in 1JCH is attributed to an increased overlap of the H-bonding σ orbital with the antibonding σ* orbitals of the vicinal C−H bonds." @default.
• W2012144519 created "2016-06-24" @default.
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• W2012144519 creator A5080505874 @default.
• W2012144519 date "2006-03-02" @default.
• W2012144519 modified "2023-10-17" @default.
• W2012144519 title "¹<i>J</i>_CH Correlates with Alcohol Hydrogen Bond Strength" @default.
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• W2012144519 doi "https://doi.org/10.1021/jo052389k" @default.
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