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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012144875> ?p ?o ?g. }

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• W2012144875 abstract "The multi-gram scale preparation of halide free lipophilic borate salts from inexpensive precursor compounds 3,3′,5,5′-tetra-tert-butyl-2,2′-biphenol and tetrahydridoboranate salts is reported. The so-called “bortebate” anion is more stable against water and bases than its aluminum analog “altebate”, but bortebate formation is significantly slower. Bortebate salts are highly soluble in hydrocarbon solvents, e.g. >35 mmol/L lithium bortebate in pentane at 20 °C. Quantitative salt metathesis reactions between sodium bortebate and halide salts can be easily achieved by precipitation of the sodium halide in methylene chloride." @default.
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• W2012144875 date "2011-04-01" @default.
• W2012144875 modified "2023-09-27" @default.
• W2012144875 title "Synthesis, structure, and unprecedented solubility of lipophilic borate salts" @default.
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• W2012144875 doi "https://doi.org/10.1016/j.ica.2010.12.039" @default.
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