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- W2012146148 abstract "In this paper, the newly prepared ZnO/HZSM-5 nanocomposites were suggested as the promising alternative materials for conventional means of waste water treatment. The combination effect of adsorption–photodegradation for the removal of 4-nitrophenol (4-NPh), as a biorefractory pollutant, occurred successfully when 7 wt.% of ZnO nanoparticles were incorporated in HZSM-5 zeolite. It was found that both the hydrophobicity and size-selectivity of HZSM-5 toward 4-NPh enhanced the adsorption process. The photodegradation of 4-NPh solutions was performed under UV irradiation and the influence of various parameters such as ZnO loading amount, pH dependence and initial concentration of 4-NPh were investigated. The results indicated that during the fixed reaction time (90 min) about 91% total organic carbon of solution, containing 4-NPh (20 mgl− 1) was removed at pH = 5. Batch kinetic studies were conducted to evaluate the adsorption–photodegradation process. The pseudo-second-order fit well over the range of reaction time. It can be suggested that encapsulating ZnO clusters in the zeolites is a proper way to inhibit the agglomeration of ZnO nanoparticles and also to retard the recombination of photogenerated electron–hole in photocatalytic activity." @default.
- W2012146148 created "2016-06-24" @default.
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- W2012146148 date "2012-02-01" @default.
- W2012146148 modified "2023-09-24" @default.
- W2012146148 title "Efficient adsorption-photodegradation of 4-nitrophenol in aqueous solution by using ZnO/HZSM-5 nanocomposites" @default.
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- W2012146148 doi "https://doi.org/10.1016/j.desal.2011.11.031" @default.
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