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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012147522> ?p ?o ?g. }

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• W2012147522 abstract "A metallocene/MAO-based solid olefin polymerization catalyst has been developed using chemically functionalized nanoparticles (carboxylate−alumoxanes) as a well-defined substrate. Reaction of p-hydroxybenzoate−alumoxane (p-HB-A) nanoparticles, formed from the acid with boehmite, with methylalumoxane (MAO) results in a solid nanoparticle-based MAO (n-MAO), which in combination with zirconocenes [including Cp2ZrCl2, Cp2ZrMe2, and (nBuCp)2ZrCl2] produces an active solid catalyst for olefin polymerization. The catalytic activity of the n-MAO-based catalyst is comparable to the homogeneous analogue and a traditional silica-supported catalyst under identical reaction conditions and with the same Al(MAO):Zr ratio. The n-MAO approach offers the potential of the MAO being easily chemically modified." @default.
• W2012147522 created "2016-06-24" @default.
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• W2012147522 date "2002-01-29" @default.
• W2012147522 modified "2023-10-16" @default.
• W2012147522 title "A Chemically Functionalized Carboxylate−Alumoxane Nanoparticle Support for Olefin Polymerization Catalysts" @default.
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• W2012147522 doi "https://doi.org/10.1021/ma010314m" @default.
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