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- W2012149977 abstract "Seventeen pairs of diastereomeric cobalt(III) complexes were subject to paper chromatography using ten multi-component solvent systems, and nineteen diastereomeric pairs were chromatographed on silica gel G and aluminium oxide G thin layers by the use of sixteen single-component and fourteen multi-component solvent systems. It was established that in the paper chromatographic separations of complexes containing coordinated l-amino acids the diastereomers having λ absolute configurations exhibited higher RF values than those with Δ absolute configurations, in all the five homologous series studied, regardless of the solvent system used. However, in the thin-layer chromatographic separations on silica gel G and aluminium oxide G, respectively, the diastereomers having the same absolute configuration and containing coordinated amino acids of the same configuration always exhibited higher (or lower) RF values only if they belonged to the same homologous series." @default.
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- W2012149977 date "1982-11-01" @default.
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- W2012149977 title "Effect of the absolute configuration of cobalt(III) complexes on their chromatographic behaviour" @default.
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