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• W2012150706 abstract "High-spin Ni(II) complexes of the linear pentadentate ligand 2,6-bis([2′-aminophenylthio]methyl)pyridine (Batp) and the tridentate ligands ([2′-aminophenylthio]ethyl)pyridine (Atep) 1,5-bis(N-methylbenzimidazol-2′-yl)-3-oxapentane (Mbeo) have been prepared. Crystal structures of the complexes [Ni(Batp)(H2O)](CF3SO3)2 (2) and [Ni(Atep)2](ClO4)2 (4) reveal pseudooctahedral coordination. Tetragonal distortion in [Ni(Mbeo)2](ClO4)2 (5) is evident from the longer Ni–O and shorter Ni–N bond lengths. From the electronic spectrum of 5, the tetragonal distortion parameter Dt and the in-plane Dqxy and axial Dqz ligand field parameters are calculated. The three Ni(II) complexes exhibit irreversible cathodic electrochemistry." @default.
• W2012150706 created "2016-06-24" @default.
• W2012150706 creator A5055457149 @default.
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• W2012150706 date "2000-10-01" @default.
• W2012150706 modified "2023-10-16" @default.
• W2012150706 title "Some nickel(II) complexes with pentadentate and tridentate heterocyclic N- and S-donor ligands" @default.
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• W2012150706 doi "https://doi.org/10.1016/s0020-1693(00)00189-4" @default.
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