Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012151915> ?p ?o ?g. }
- W2012151915 endingPage "12324" @default.
- W2012151915 startingPage "12324" @default.
- W2012151915 abstract "Eight new Zn(II) coordination polymers based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates, [Zn(dimb)(suc)·2DMF]n (1), [Zn(dimb)(mbda)·3H2O]n (2), [Zn(dimb)(adip)·DMF·2H2O]n (3), [Zn(dimb)(pma)·2.5H2O]n (4), [Zn2(dimb)(tha)2(H2O)]n (5), [Zn(dimb)(chda)·2H2O]n (6), [Zn(dimb)(obda)·DMF]n (7), [Zn(dimb)(tdga)·CH3OH]n (8) (dimb = 1,4-di(1H-imidazol-1-yl)butane, H2suc = succinic acid, H2mbda = m-benzenediacetic acid, H2adip = adipic acid, H2pma = pimelic acid, H2tha = thiophene-2,5-dicarboxylic acid, H2chda = 1,4-cyclohexanedicarboxylic acid, H2obda = o-benzenediacetic acid, H2tdga = thiodiglycolic acid; DMF = N,N′-dimethylformamide), have been synthesized and structurally characterized by single-crystal X-ray diffraction analyses, and further characterized by infrared spectra (IR), elemental analyses, powder X-ray diffractions (PXRD) and thermogravimetric analyses (TGA). Single-crystal X-ray diffraction analysis reveals that 1, 2, 4, 7 and 8 are 2D wavy 44-sql networks with different dimensions of quadrilateral window units, depending on the conformation and length of dimb and dicarboxylates. Complex 3 is a 2D a 63-hcb network incorporating a [Zn2(dimb)2] cyclic subunit. In complex 5, Zn(II) centers as 3-connected node are linked by dimb and tha to form a 3D 8-fold interpenetrating ThSi22 network. Complex 6 is a 4-connected noninterpenetrating cds network. Interestingly, an infinite T4(2)6(2) water tape and a D2h cyclic water tetramer are also found in complexes 2 and 3, respectively. In 1–8, all Zn(II) centers are located in a four-coordinated environment, and dimb and dicarboxylates are 2-connected linkers, but networks with diverse topologies are built, which indicates the linkage of central metal ion, the conformation of dimb and dicarboxylate have important influences on the resulting structures. Furthermore, the solid-state photoluminescence properties of the 1–8 were investigated at 298 and 77 K." @default.
- W2012151915 created "2016-06-24" @default.
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- W2012151915 creator A5062071376 @default.
- W2012151915 creator A5089901400 @default.
- W2012151915 date "2013-01-01" @default.
- W2012151915 modified "2023-10-07" @default.
- W2012151915 title "Eight Zn(ii) coordination networks based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates: crystal structures, water clusters, and topologies" @default.
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