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- W2012155124 abstract "The reactions of CCl3 with O(3P) and O2 and those of CCl3O2 with NO have been studied at 295 K using discharge flow methods with helium as the bath gas. The rate coefficient for the reaction of CCl3 with O was found to be (4.2 ± 0.6) × 10−11 cm3/s and that for CCl3O2 with NO was (18.6 ± 2.8) × 10−12 cm3/s with both coefficients independent of [He]. For reaction between CCl3 and O2 the rate coefficient was found to increase from 1.51 7times; 10−14 cm3/s to 7.88 × 10−14 cm3/s as the [He] increased from 3.5 × 1016 cm−3 to 2.7 × 1017 cm−3. There was no evidence for a direct two-body reaction, and it is concluded that the only product of this reaction is CCl3O2. Examination of these results for CCl3 + O2 in terms of current simplified falloff treatment suggests that the high-pressure limit for this reaction is ∼ 2.5 × 10−12 cm3/s, which may be compared with a direct measurement of the high-pressure limit of 5 × 10−12 cm3/s. A value of (5.8 ± 0.6) × 10−31 cm6/s has been obtained for k0, the coefficient in the low-pressure region. This value is compared with corresponding values found earlier for the (CH3, O2) and (CF3, O2) systems and with estimates based on unimolecular rate theory." @default.
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- W2012155124 date "1984-05-01" @default.
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- W2012155124 title "Kinetics of the reactions of CCl3 with O and O2 and of CCl3O2 with NO at 295 K" @default.
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- W2012155124 doi "https://doi.org/10.1002/kin.550160508" @default.
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