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- W2012156626 abstract "Abstract Cu L2,3-edge X-ray absorption spectra for (Me2-DCNQI)2Li1−xCux alloys (Me2-DCNQI: 2,5-dimethyl-N,N′-dicyanoquinonediimine) were measured in order to investigate the local electronic structure around Cu atoms. Both in the Cu L3- and L2-edge regions, (Me2-DCNQI)2Cu (x=1) shows a characteristic band higher in energy than the lowest sharp band associated with the transitions to the Cu 3d hole; on the other hand, K3Cu(CN)4 with Cu 3d10 configuration shows only the higher-energy band. These higher-energy bands arise from the transitions to the lowest unoccupied molecular orbitals of Me2-DCNQI and CN ligand molecules, respectively, where the intensity comes from the Cu 3d components through strong hybridization between metal and ligand. The spectral feature does not change even if the x value is reduced to less than 0.1, indicating that the alloys have nearly the same covalent bond between Cu and Me2-DCNQI as (Me2-DCNQI)2Cu (x=1), independent of the substitution. This demonstrates that we can control the filling and the dimensionality of electronic structure in Me2-DCNQI charge-transfer complexes through the replacement of Li by Cu." @default.
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- W2012156626 date "2004-03-01" @default.
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- W2012156626 title "Cu L2,3-edge X-ray absorption spectra of (2,5-dimethyl-N,N′-dicyanoquinonediimine)2Li1−xCux alloys" @default.
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- W2012156626 doi "https://doi.org/10.1016/j.chemphys.2003.11.023" @default.
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