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- W2012157056 abstract "ESR spectra of the Cu 2+ ion, doped in a di-[(2-aminoethyl)amine)]-di-isothiocyanato-cadmate(II) lattice in its single-crystal form, have been investigated. Cd(den) (SCN) 2 has unusual coordination, in that two separate CdN 6 and CdN 4 S 2 entities are present in the unit cell. Cu 2+ substitutes predominantly for the CdN 6 structural unit, and spectra recorded at both ambient and liquid-nitrogen temperatures are fitted to a spin-Hamiltonian of orthorhombic symmetry. In contrast, the weak spectral lines corresponding to the Cu 2+ ions which substitute for the CdN 4 S 2 structural unit are characteristic of axial symmetry. A single-crystal study was also made on di-[(2-aminoethyl)amine]-di-isothiocyanato- copper(II), in which the Cu 2+ ion has a coordination number of five and “C 2v ” point symmetry. A comparison of the spectral features shown in the two lattices was made and some interesting conclusions are drawn." @default.
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- W2012157056 date "1980-05-01" @default.
- W2012157056 modified "2023-09-26" @default.
- W2012157056 title "Host-lattice effects on the electron spin resonance spectra of copper(II) complexes in diluted and undiluted forms" @default.
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- W2012157056 doi "https://doi.org/10.1016/0022-2860(80)80138-4" @default.
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