Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012157361> ?p ?o ?g. }
- W2012157361 endingPage "858" @default.
- W2012157361 startingPage "851" @default.
- W2012157361 abstract "Abstract The synthesis of discotic liquid crystal materials based on the triphenylene core normally involves the preparation of hexahydroxytriphenylene. This has traditionally been accomplished by a chloranil promoted trimerization of 1,2-dimethoxy-benzene followed by demethylation of the hexamethoxytriphenylene produced. Hexahydroxytriphenylene is subsequently alkylated to give the required derivative. The overall yield of this three step procedure is low and it is difficult to perform on a large scale. It is herein shown that a modified procedure using iron III chloride instead of chloranil yields hexa-alkoxytriphenylenes in a single step. The reaction is high yielding and can be performed on a large scale. This also provides a better route than those currently available for making the unsymmetrically substituted tri-phenylenes required in the synthesis of polymeric discotic liquid crystals. Some related elaborations of the triphenylene nucleus are also discussed." @default.
- W2012157361 created "2016-06-24" @default.
- W2012157361 creator A5000126822 @default.
- W2012157361 creator A5014845353 @default.
- W2012157361 creator A5052094444 @default.
- W2012157361 creator A5074540926 @default.
- W2012157361 creator A5077313370 @default.
- W2012157361 date "1993-12-01" @default.
- W2012157361 modified "2023-10-16" @default.
- W2012157361 title "The synthesis of triphenylene-based discotic mesogens New and improved routes" @default.
- W2012157361 cites W1609109850 @default.
- W2012157361 cites W1981413315 @default.
- W2012157361 cites W2036573544 @default.
- W2012157361 cites W2040383510 @default.
- W2012157361 cites W2054154089 @default.
- W2012157361 cites W2057351548 @default.
- W2012157361 cites W2058804846 @default.
- W2012157361 cites W2062531855 @default.
- W2012157361 cites W2072918521 @default.
- W2012157361 cites W2127897744 @default.
- W2012157361 cites W2138006038 @default.
- W2012157361 cites W2147059018 @default.
- W2012157361 cites W2951749096 @default.
- W2012157361 cites W3134410488 @default.
- W2012157361 doi "https://doi.org/10.1080/02678299308036504" @default.
- W2012157361 hasPublicationYear "1993" @default.
- W2012157361 type Work @default.
- W2012157361 sameAs 2012157361 @default.
- W2012157361 citedByCount "176" @default.
- W2012157361 countsByYear W20121573612012 @default.
- W2012157361 countsByYear W20121573612013 @default.
- W2012157361 countsByYear W20121573612014 @default.
- W2012157361 countsByYear W20121573612015 @default.
- W2012157361 countsByYear W20121573612016 @default.
- W2012157361 countsByYear W20121573612017 @default.
- W2012157361 countsByYear W20121573612018 @default.
- W2012157361 countsByYear W20121573612019 @default.
- W2012157361 countsByYear W20121573612020 @default.
- W2012157361 countsByYear W20121573612021 @default.
- W2012157361 countsByYear W20121573612022 @default.
- W2012157361 countsByYear W20121573612023 @default.
- W2012157361 crossrefType "journal-article" @default.
- W2012157361 hasAuthorship W2012157361A5000126822 @default.
- W2012157361 hasAuthorship W2012157361A5014845353 @default.
- W2012157361 hasAuthorship W2012157361A5052094444 @default.
- W2012157361 hasAuthorship W2012157361A5074540926 @default.
- W2012157361 hasAuthorship W2012157361A5077313370 @default.
- W2012157361 hasConcept C106159729 @default.
- W2012157361 hasConcept C111771559 @default.
- W2012157361 hasConcept C114137331 @default.
- W2012157361 hasConcept C13274807 @default.
- W2012157361 hasConcept C134121241 @default.
- W2012157361 hasConcept C147498150 @default.
- W2012157361 hasConcept C161790260 @default.
- W2012157361 hasConcept C162324750 @default.
- W2012157361 hasConcept C164361826 @default.
- W2012157361 hasConcept C178790620 @default.
- W2012157361 hasConcept C185592680 @default.
- W2012157361 hasConcept C191897082 @default.
- W2012157361 hasConcept C192562407 @default.
- W2012157361 hasConcept C2777630638 @default.
- W2012157361 hasConcept C2779539529 @default.
- W2012157361 hasConcept C3535393 @default.
- W2012157361 hasConcept C49040817 @default.
- W2012157361 hasConceptScore W2012157361C106159729 @default.
- W2012157361 hasConceptScore W2012157361C111771559 @default.
- W2012157361 hasConceptScore W2012157361C114137331 @default.
- W2012157361 hasConceptScore W2012157361C13274807 @default.
- W2012157361 hasConceptScore W2012157361C134121241 @default.
- W2012157361 hasConceptScore W2012157361C147498150 @default.
- W2012157361 hasConceptScore W2012157361C161790260 @default.
- W2012157361 hasConceptScore W2012157361C162324750 @default.
- W2012157361 hasConceptScore W2012157361C164361826 @default.
- W2012157361 hasConceptScore W2012157361C178790620 @default.
- W2012157361 hasConceptScore W2012157361C185592680 @default.
- W2012157361 hasConceptScore W2012157361C191897082 @default.
- W2012157361 hasConceptScore W2012157361C192562407 @default.
- W2012157361 hasConceptScore W2012157361C2777630638 @default.
- W2012157361 hasConceptScore W2012157361C2779539529 @default.
- W2012157361 hasConceptScore W2012157361C3535393 @default.
- W2012157361 hasConceptScore W2012157361C49040817 @default.
- W2012157361 hasIssue "6" @default.
- W2012157361 hasLocation W20121573611 @default.
- W2012157361 hasOpenAccess W2012157361 @default.
- W2012157361 hasPrimaryLocation W20121573611 @default.
- W2012157361 hasRelatedWork W1582260747 @default.
- W2012157361 hasRelatedWork W1987165561 @default.
- W2012157361 hasRelatedWork W1991534429 @default.
- W2012157361 hasRelatedWork W2009349443 @default.
- W2012157361 hasRelatedWork W2016963989 @default.
- W2012157361 hasRelatedWork W2025269502 @default.
- W2012157361 hasRelatedWork W2071970197 @default.
- W2012157361 hasRelatedWork W2093780086 @default.
- W2012157361 hasRelatedWork W2388583142 @default.
- W2012157361 hasRelatedWork W4296546669 @default.
- W2012157361 hasVolume "15" @default.
- W2012157361 isParatext "false" @default.
- W2012157361 isRetracted "false" @default.