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- W2012160522 abstract "Abstract We introduce here a strategy that enables effective addition of lithium enolates of acetates to aldimines. The new method depends strongly on the use of ortho-alkoxy (or ortho-fluoro) aniline-derived aldimines which found to have a potential effect on the enolate addition. This scope was expanded to the asymmetric process using the chiral acetate, which has optically pure 2,6-bis(2-isopropylphenyl)-3,5-dimethylphenol as a chiral auxiliary with axial chirality. A Lewis acid additive is likely to have a complementary role in the pronounced activation of imine functionalities in the Mannich-type addition of the bulky chiral acetate." @default.
- W2012160522 created "2016-06-24" @default.
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- W2012160522 date "2010-05-26" @default.
- W2012160522 modified "2023-09-26" @default.
- W2012160522 title "ChemInform Abstract: Asymmetric Mannich-Type Reactions with a Chiral Acetate: Effect of Lewis Acid on Activation of Aldimine." @default.
- W2012160522 cites W2953254809 @default.
- W2012160522 doi "https://doi.org/10.1002/chin.200121024" @default.
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