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• W2012165649 abstract "In the presence of NiCl2L2/NaBH4/ROH catalysts, norbornene dimerizes to yield dimers 4 and 5. With PPh3 as a ligand and MeOH as solvent the 45 selectivity can reach 2080, whereas with dppe in the same solvent, dimer 4 is obtained exclusively. We suggest that the active catalyst is a zero-valent nickel species which is generated in situ from a transient nickel hydride complex. Exo-trans-exo-nickelacyclopentane, formed by oxidative coupling of two norbornene units on Ni(0), is suggested as the key intermediate in the catalytic cycle which is proposed." @default.
• W2012165649 created "2016-06-24" @default.
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• W2012165649 date "1987-06-01" @default.
• W2012165649 modified "2023-09-25" @default.
• W2012165649 title "Nickel-catalyzed dimerization of norbornene" @default.
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• W2012165649 doi "https://doi.org/10.1016/0304-5102(87)80092-5" @default.
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