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- W2012167875 abstract "Abstract High-temperature equilibrium calculations were used to study factors influencing the formation of S 2 under conditions appropriate for the flame photometric detection of sulphur. The calculations show that there is a maximum in the formation of S 2 for α = 0.52 (α = 2φ o2 /φH 2 , φ denotes the flow rate) compared with experimentally found values of 0.46–0.56. Ths role of carbon in decreasing the emission signal from S 2 is calculated and discussed. The depressive effect of hydrocarbons can be overcome by oxidizing to carbon dioxide prior to introduction into the flame. The non-linearity of the calibration curve for higher concentrations of sulphur can also be predicted from the calculations." @default.
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- W2012167875 date "1978-09-01" @default.
- W2012167875 modified "2023-09-24" @default.
- W2012167875 title "Formation of s2 under conditions appropriate to flame photometric sulphur detection" @default.
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- W2012167875 doi "https://doi.org/10.1016/s0003-2670(01)93337-9" @default.
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